| June 24, 1958 | | World Cup | Semi-final | 1958 |
| December 10, 1961 | | Friendly | | 1961 |
| October 20, 1962 | | Friendly | | 1962 |
| April 28, 1963 | | Friendly | | 1963 |
| May 05, 1963 | | Friendly | | 1963 |
| May 15, 1963 | | Cup Winners' Cup | Final | 1962-1963 |
| April 15, 1964 | | European Cup | Semi-final, 1st leg | 1963-1964 |
| March 17, 1965 | | European Cup | Quarter-finals, 2nd leg | 1964-1965 |
| September 08, 1965 | | European Cup | Round of 32, 1st leg | 1965-1966 |
| March 02, 1966 | | Inter-Cities Fairs Cup | Round of 16, play-off | 1965-1966 |
| July 16, 1966 | | World Cup | Group stage, matchday 2 | 1966 |
| July 20, 1966 | | World Cup | Group stage, matchday 3 | 1966 |
| July 28, 1966 | | World Cup | Third-place match | 1966 |
| September 07, 1966 | | Euro Qualification | Matchday 1 | 1966 |
| December 04, 1966 | | Liga 1ª División | Jornada 12 | 1966-1967 |
| January 08, 1967 | | Liga 1ª División | Jornada 16 | 1966-1967 |
| February 19, 1967 | | Liga 1ª División | Jornada 21 | 1966-1967 |
| June 05, 1968 | | Euro | Semi-final | 1968 |
| June 05, 1968 | | Euro | Semi-final | 1968 |
| October 02, 1968 | | European Cup | Round of 32, 2nd leg | 1968-1969 |
